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Note for CONCRETE TECHNOLOGY - CT by MD. Åbđūllãh

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Concrete Technology Unit-I Cement in its broadest term means any substance which acts as a binding agent for materials natural cement (Roman Cement) is obtained by burning and crushing the stones containing clay, carbonates of lime and some amount of carbonate of magnesia. The clay content in such stones is about 20 to 40 percent. Natural cement resembles very closely eminent hydraulic lime. It is not strong as artificial cement, so it has limited use in practice. Artificial cement is obtained by burning at very high temperature a mixture of calcareous and rgillaceous materials in correct proportion. Calcined product is known as clinker. A small quantity of gypsum is added to clinker and it is then pulverized into very fine powder is known as cement. Cement was invented by a mason Joseph Aspdin of leeds in England in 1824. The common variety of artificial cement is known as normal setting cement or ordinary cement or Portland cement. Ingradeints – Functions Ordinary Portland cement contains two basic ingredients, namely argillaceous and calcareous. In argillaceous materials, clay predominates and in calcareous materials, calcium carbonate predominates. Good ordinary cement contains following ingradients. 1. Lime (cao) ………. …………………………………..62% 2. silica (Sio2) ………. …………………………………22% 3. Aluminca(Al2 u3) ………………………………….. 5% 4. Calcium sulphate (CaSo4) …………………………. 4% 5. Iron Oxide (Fe2 O3) ……………………………….. 3% 6. Magnescia (Mgo) ………………………………….. 2% 7. Sulphur ………. ……………………………………..1% 8. Alkalies …………………………………………….. 1% Functions of Ingradients: 1. Lime: Lime is the important ingredient of cement and its proportion is to be maintained carefully. Lime in excess makes the cement unsound and causes the cement to expand and disintegrate. On the other hand, if lime is in deficiency the strength of the cement is decreased and it causes cement to set quickly 2. Silica: This also an important ingredient of cement and it gives or imparts quick setting property to imparts strength to cement. 3.Alumina: This ingredient imparts quick setting properly to cement. Express alumina weakens the cement. 4. Calcium Sulphate: This ingredient is in the form of gypsum and its function is to increase the initial setting time of cement. 5. Magnesia: The small amount of this ingredient imparts hardness and colour to cement. 6. Sulphur: A very small amount of sulphur is useful in making sound cement. If it is in excess, it causes the cement to become unsound. 7. Alkalies: Most of the alkalies present in raw material are carried away by the flue gases during heating and only small quantity will be left. If they are in excess in cement, efflorescence is caused Manufacture of Portland Cement The raw materials required for manufacture of Portland cement are calcareous materials, such as limestone or chalk, and argillaceous material such as shale or clay. Cement factories are established 1

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where these raw materials are available in plenty. Cement factories have come up in many regions in India, eliminating the inconvenience of long distance transportation of raw and finished materials. The process of manufacture of cement consists of grinding the raw materials, mixing them intimately in certain proportions depending upon their purity and composition and burning them in a kiln at a temperature of about 1300 to 1500°C, at which temperature, the material sinters and partially fuses to form nodular shaped clinker. The clinker is cooled and ground to fine powder with addition of about 3 to 5% of gypsum. The product formed by using this procedure is Portland cement. There are two processes known as “wet” and “dry” processes depending upon whether the mixing and grinding of raw materials is done in wet or dry conditions. With a little change in the above process we have the semi-dry process also where the raw materials are ground dry and then mixed with about 10-14 per cent of water and further burnt to clinkering Temperature Dry Process In the dry and semi-dry process the raw materials are crushed dry and fed in correct proportions into a grinding mill where they are dried and reduced to a very fine powder. The dry powder called the raw meal is then further blended and corrected for its right composition and mixed by means of compressed air. The aerated powder tends to behave almost like liquid and in about one hour of aeration a uniform mixture is obtained. The blended meal is further sieved and fed into a rotating disc called granulator. A quantity of water about 12 per cent by wright is added to make the blended meal into pellets. This is done to permit air flow for exchange of heat for further chemical reactions and conversion of the same into clinker further in the rotary kiln. The equipments used in the dry process kiln is comparatively smaller. The process is quite economical. The total consumption of coal in this method is only about 100 kg when compared to the requirement of about 350 kg for producing a ton of cement in the wet process. During March 1998, in India, there were 173 large plants operating, out of which 49 plants used wet process, 115 plants used dry process and 9 plants used semi-dry process. Since the time of partial liberalisation of cement industry in India (1982), there has been an upgradation in the quality of cement. Many cement companies upgraded their plants bothin respect of capacity and quality. Types of Cement (a) Ordinary Portland cement • Ordinary Portland Cement 33 Grade– IS 269: 1989 • Ordinary Portland Cement 43 Grade– IS 8112: 1989 • Ordinary Portland Cement 53 Grade– IS 12269: 1987 (b) Rapid Hardening Cement – IS 8041: 1990 (c) Extra Rapid Hardening Cement – – (d) Sulphate Resisting Cement – IS 12330: 1988 (e) Portland Slag Cement – IS 455: 1989 (f) Quick Setting Cement – – (g) Super Sulphated Cement – IS 6909: 1990 (h) Low Heat Cement – IS 12600: 1989 (j) Portland Pozzolana Cement – IS 1489 (Part I) 1991 (fly ash based) – IS 1489 (Part II) 1991 (claimed clay based) (k) Air Entraining Cement – – (l ) Colored Cement: White Cement – IS 8042: 1989 (m) High Alumina Cement – IS 6452: 1989 (n) Very High Strength Cement – – Ordinary Portland Cement Ordinary Portland cement (OPC) is by far the most important type of cement. All the discussions that we have done in the previous chapter and most of the discussions that are going to be done in the coming chapters relate to OPC. Prior to 1987, there was only one grade of OPC which was governed by IS 2691976. After 1987 higher grade cements were introduced in India. The OPC was classified into three grades, namely 33 grade, 43 grade and 53 grade depending upon the strength of the cement at 28 days 2

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when tested as per IS 4031- 1988. If the 28 days strength is not less than 33N/mm2, it is called 33 grade cement, if the strength is not less than 43N/mm2, it is called 43grade cement, and if the strength is not less then 53 N/mm2, it is called 53 grade cement. But the actual strength obtained by these cements at the factory are much higher than the BIS specifications. The physical and chemical properties of 33, 43 and 53 grade OPC Rapid Hardening Cement (IS 8041–1990) This cement is similar to ordinary Portland cement. As the name indicates it develops strength rapidly and as such it may be more appropriate to call it as high early strength cement. It is pointed out that rapid hardening cement which develops higher rate of development of strength should not be confused with quick-setting cement which only sets quickly. Rapid hardening cement develops at the age of three days, the same strength as that is expected of ordinary Portland cement at seven days. The rapid rate of development of strength is attributed to the higher fineness of grinding (specific surface not less than 3250 sq. cm per gram) and higher C3S and lower C2S content. A higher fineness of cement particles expose greater surface area for action of water and also higher proportion of C3S results in quicker hydration. Consequently, capid hardening cement gives out much greater heat of hydration during the early period. Therefore, rapid hardening cement should not be used in mass concrete construction. The use of rapid heading cement is recommended in the following situations: (a) In pre-fabricated concrete construction. (b) Where formwork is required to be removed early for re-use elsewhere, (c ) Road repair works, (d ) In cold weather concrete where the rapid rate of development of strength reduces the vulnerability of concrete to the frost damage. The physical and chemical requirements of rapid hardening cement are shown in Tables2.5 and 2.6 respectively. Extra Rapid Hardening Cement Extra rapid hardening cement is obtained by intergrinding calcium chloride with rapid hardening Portland cement. The normal addition of calcium chloride should not exceed 2 per cent by weight of the rapid hardening cement. It is necessary that the concrete made by using extra rapid hardening cement should be transported, placed and compacted and finished within about 20 minutes. It is also necessary that this cement should not be stored for more than a month. Extra rapid hardening cement accelerates the setting and hardening process. A large quantity of heat is evolved in a very short time after placing. The acceleration of setting, hardening and evolution of this large quantity of heat in the early period of hydration makes the cement very suitable for concreting in cold weather, Sulphate Resisting Cement (IS 12330–1988) Ordinary Portland cement is susceptible to the attack of sulphates, in particular to the action of magnesium sulphate. Sulphates react both with the free calcium hydroxide in setcement to form calcium sulphate and with hydrate of calcium aluminate to form calcium sulphoaluminate, the volume of which is approximately 227% of the volume of the original aluminates. Their expansion within the frame work of hadened cement paste results in cracks and subsequent disruption. Solid sulphate do not attack the cement compound. Sulphates in solution permeate into hardened concrete and attack calcium hydroxide, hydrated calcium aluminate and even hydrated silicates. The above is known as sulphate attack. Sulphate attack is greatly accelerated if accompanied by alternate wetting and drying which normally takes place in marine structures in the zone of tidal variations. To remedy the sulphate attack, the use of cement with low C3A content is found to be effective. Such cement with low C3 A and comparatively low C4AF content is known as Sulphate Resisting Cement. In other words, this cement has a high silicate content. Thespecification generally limits the C3A content to 5 per cent. Portland Slag Cement (PSC) (IS 455–1989) Portland slag cement is obtained by mixing Portland cement clinker, gypsum and granulated blast furnace slag in suitable proportions and grinding the mixture to get a thorough and intimate mixture between the constituents. It may also be manufactured by separately grinding Portland cement clinker, gypsum and ground granulated blast furnace slag and later mixing them intimately. The resultant product is a cement 3

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which has physical properties similar to those of ordinary Portland cement. In addition, it has low heat of hydration and is relatively better resistant to chlorides, soils and water containing excessive amount of sulphates or alkali metals, alumina and iron, as well as, to acidic waters, and therefore, this can be used for marine works with advantage. Quick Setting Cement This cement as the name indicates sets very early. The early setting property is brought out by reducing the gypsum content at the time of clinker grinding. This cement is required to be mixed, placed and compacted very early. It is used mostly in under water construction where pumping is involved. Use of quick setting cement in such conditions reduces the pumping time and makes it economical. Quick setting cement may also find its use in some typical grouting operations. Super Sulphated Cement (IS 6909–1990) Super sulphated cement is manufactured by grinding together a mixture of 80-85 per cent granulated slag, 10-15 per cent hard burnt gypsum, and about 5 per cent Portland cement clinker. The product is ground finer than that of Portland cement. Specific surface must not be less than 4000 cm2 per gm. The supersulphated cement is extensively used in Belgium, where it is known as “ciment metallurgique sursulfate.” In France, it is known as “ciment sursulfate”. This cement is rather more sensitive to deterioration during storage than Portland cement. Super-sulphated cement has a low heat of hydration of about 40-45 calories/gm at 7 days and 45-50 at 28 days. This cement has high sulphate resistance. Because of this property this cement is particularly recommended for use in foundation, where chemically aggressive conditions exist. As super-sulphated cement has more resistance than Portland blast furnace slag cement to attack by sea water, it is also used in the marine works. Other areas where super-sulphated cement is recommended include the fabrication of reinforced concrete pipes which are likely to be buried in sulphate bearing soils. The substitution of granulated slag is responsible for better resistance to sulphate attack. Portland Pozzolana Cement (IS 1489–1991) The history of pozzolanic material goes back to Roman’s time. The descriptions and details of pozzolanic material will be dealt separately under the chapter ‘Admixtures’. However a brief description is given below. Portland Pozzolana cement (PPC) is manufactured by the intergrinding of OPC clinker with 10 to 25 per cent of pozzolanic material (as per the latest amendment, it is 15 to 35%). A pozzolanic material is essentially a silicious or aluminous material which while in itself possessing no cementitious properties, which will, in finely divided form and in the presence of water, react with calcium hydroxide, liberated in the hydration process, at ordinary temperature, to form compounds possessing cementitious properties. The pozzolanic materials generally used for manufacture of PPC are calcined clay (IS 1489 part 2 of 1991) or fly ash (IS 1489 part I of 1991). Fly ash is a waste material, generated in the thermal power station, when powdered coal is used as a fuel. These are collected in the electrostatic precipitator. (It is called pulverised fuel ash in UK Coloured Cement (White Cement IS 8042–1989) For manufacturing various coloured cements either white cement or grey Portland cement is used as a base. The use of white cement as a base is costly. With the use of grey cement only red or brown cement can be produced. Coloured cement consists of Portland cement with 5-10 per cent of pigment. The pigment cannot be satisfactorily distributed throughout the cement by mixing, and hence, it is usual to grind the cement and pigment together. The properties required of a pigment to be used for coloured cement are the durability of colour under exposure to light and weather, a fine state of division, a chemical composition such that the pigment is neither effected by the cement nor detrimental to it, and the absence of soluble salts.The process of manufacture of white Portland cement is nearly same as OPC. As the raw materials, particularity the kind of limestone required for manufacturing white cement is only available around Jodhpur in Rajasthan, two famous brands of white cement namely Birla White and J.K. White Cements are manufactured near Jodhpur. The raw materials used are high purity limestone (96% CaCo3 and less than 0.07% iron oxide). The other raw materials are china clay with iron content of about 0.72 to 0.8%, silica sand, flourspar as flux and selenite as retarder. The fuels used are refined furnace oil (RFO) or gas. Sea shells and coral can also be used as raw materials for production of white cemen 4

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